Toward the discovery of new soft quasicrystals: From a numerical study viewpoint

Tomonari Dotera

J. Polym. Sci. Part B: Polym. Phys. 50, 155-167 (2012).

The 2011 Nobel Prize for Chemistry was awarded for "the discovery of quasicrystals" -crystals that are ordered but not periodic, and possess gforbiddenh symmetries. Such crystals in soft matter have potential photonic applications since they can be engineered with remarkable optical properties and photonic bandgaps. On page 155, Tomonari Dotera provides a quick introduction of quasicrytals, rational design, and realization of esoftf?including block copolymer, colloid, and liquid crystalline?quasicrystals. Approaches to finding new quasicrystals is a particular focus. The cover depicts a rendering of a potion of the (3.3.4.3.4) Archimedean tiling phase from ABC star terpolymers, closely related to the first discovery of polymeric quasicrystals.

Abstract:
This is a progress review of an emerging research front: soft quasicrystals including liquid crystalline dendrons, nanoparticles, mesoporous silica, colloids, ABC star and linear terpolymers, and even water and silicon. As an aid to readers, we explain the basics of quasicrystals developed in solid-state physics: orders in quasicrystals, higher dimensional crystallography, approximants, phason randomness, and the origin of quasicrystal formation. Then we review some numerical studies from early to recent ones. Our main purpose is to elucidate how to construct quasicrystalline structures: The introduction of additional components or a new length-scale is the key to discover new quasicrystals. As a case study, we describe our recent studies on ABC star terpolymer systems and present the results of simulations of dodecagonal polymeric quasicrystals. In the case of dodecagonal quasicrystals, one easily finds that the key is to search square-triangle tiling structures with changing components. Application to photonic quasicrystals is reviewed as well. Our hope is that this review will contribute furthering quasicrystal chemistry.

Keywords:
ABC star polymer;Archimedean tiling;block copolymer;mircophase separation;photonic crystal;quasicrystal;self-assembly;simulation;soft matter;theory